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http://hdl.handle.net/10261/180448
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Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Esteruelas, Miguel A. | es_ES |
dc.contributor.author | Fernández, Israel | es_ES |
dc.contributor.author | Martínez, Antonio | es_ES |
dc.contributor.author | Oliván, Montserrat | es_ES |
dc.contributor.author | Oñate, Enrique | es_ES |
dc.contributor.author | Vélez, Andrea | es_ES |
dc.date.accessioned | 2019-04-24T08:56:53Z | - |
dc.date.available | 2019-04-24T08:56:53Z | - |
dc.date.issued | 2019 | - |
dc.identifier.citation | Inorganic Chemistry 58(8): 4712-4717 (2019) | es_ES |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/10261/180448 | - |
dc.description.abstract | The tris(boryl) complex Ir(Bcat)3{κ3-P,O,P-[xant(PiPr2)2]} [Bcat = catecholboryl; xant(PiPr2)2 = 9,9-dimethyl-4,5-bis(diisopropylphosphino)xanthene] has been prepared and characterized by X-ray diffraction analysis. The boryl ligands are disposed in a mer arrangement. The Ir–B bonds situated mutually trans are ∼0.1 Å longer than that disposed cis to the other two. An energy decomposition analysis method coupled to natural orbitals for chemical valence has revealed that the level of π-back-donation from the metal to the pz atomic orbital of the boron atom decreases ∼43% in the longer bonds with respect to the shorter one, while the level of σ-bonding interaction diminishes by only ∼8%. | es_ES |
dc.description.sponsorship | Financial support from the MINECO of Spain (Projects CTQ2017-82935-P, CTQ2016-78205-P, Red de Excelencia Consolider CTQ2016-81797-REDC), the Gobierno de Aragón (Group E06_17R and predoctoral contract to A.M.), FEDER, and the European Social Fund is acknowledged. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/CTQ2017-82935-P | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2016-78205-P | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2016-81797-REDC | es_ES |
dc.relation.isversionof | Postprint | es_ES |
dc.rights | openAccess | en_EN |
dc.title | Iridium-promoted B–B bond activation: Preparation and X-ray diffraction analysis of a mer-tris(boryl) complex | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1021/acs.inorgchem.9b00339 | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | https://doi.org/10.1021/acs.inorgchem.9b00339 | es_ES |
dc.identifier.e-issn | 1520-510X | - |
dc.embargo.terms | 2020-03-27 | es_ES |
dc.contributor.funder | Gobierno de Aragón | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | es_ES |
dc.contributor.funder | Ministerio de Ciencia, Innovación y Universidades (España) | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.relation.csic | Sí | es_ES |
oprm.item.hasRevision | no ko 0 false | * |
dc.identifier.funder | http://dx.doi.org/10.13039/501100010067 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.grantfulltext | open | - |
item.openairetype | artículo | - |
item.fulltext | With Fulltext | - |
item.languageiso639-1 | en | - |
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trisboryl manuscript-REVISED.pdf | 293,89 kB | Adobe PDF | Visualizar/Abrir |
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