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Título: | Nucleophilic additions to coordinated 1,10-phenanthroline: intramolecular, intermolecular, reversible, and irreversible |
Autor: | Arévalo, Rebeca CSIC; Menéndez, M. Isabel; López, Ramón; Merino, Isabel; Riera, Lucía CSIC ORCID; Pérez, Julio CSIC ORCID | Palabras clave: | N ligands Nucleophilic addition Phenanthroline complexes Pyridine dearomatization Rhenium carbonyls |
Fecha de publicación: | 2016 | Editor: | Wiley-VCH | Citación: | Chemistry - A European Journal 22(50): 17972-17975 (2016) | Resumen: | KN(SiMe3)2 reacts with [Re(CO)3(phen)(PMe3)]OTf via reversible addition to the phen ligand and irreversible deprotonation of the PMe3 ligand followed by intramolecular attack to phen by the deprotonated phosphane, whereas MeLi irreversibly adds to phen. The addition of MeLi has been shown to be intermolecular, unlike previously known nucleophilic additions to pyridines. | Versión del editor: | https://doi.org/10.1002/chem.201604438 | URI: | http://hdl.handle.net/10261/141420 | DOI: | 10.1002/chem.201604438 | ISSN: | 0947-6539 | E-ISSN: | 1521-3765 |
Aparece en las colecciones: | (CINN) Artículos |
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NucleophiliAdditions.pdf | 899,92 kB | Adobe PDF | Visualizar/Abrir |
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