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http://hdl.handle.net/10261/131455
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Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.contributor.author | Tian, Tian | es_ES |
dc.contributor.author | Wharmby, Michael T. | es_ES |
dc.contributor.author | Parra Soto, José Bernardo | es_ES |
dc.contributor.author | Ovín Ania, María Concepción | es_ES |
dc.contributor.author | Fairen-Jiménez, David | es_ES |
dc.date.accessioned | 2016-04-26T09:57:57Z | - |
dc.date.available | 2016-04-26T09:57:57Z | - |
dc.date.issued | 2016-02-26 | - |
dc.identifier.citation | Dalton Transactions 45(16): 6893-6900 (2016) | es_ES |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.uri | http://hdl.handle.net/10261/131455 | - |
dc.description.abstract | The flexibility and structure transition behaviour of ZIF-8 in a series of samples with different particle size has been studied using a combination of high-resolution N2 gas adsorption isotherms and, for the first time, a broad in situ PXRD and Rietveld analysis. During the stepped adsorption process, large particles showed a narrow adsorption/desorption pressure range with a shorter equilibrium time due to lower kinetic hindrance, deriving from higher amount of active sites. In situ PXRD showed that both the rotation of imidazole ring and a bend in the methyl group led to the gate opening of ZIF-8. | es_ES |
dc.description.sponsorship | This work was funded by the EPSRC IAA Partnership Development Award (RG/75759). D. F.-J. thanks the Royal Society for funding through a University Research Fellowship. We thank Diamond Light Source for beamtime at beamline I11 (visit EE9750). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Royal Society of Chemistry (UK) | es_ES |
dc.relation.isversionof | Publisher's version | es_ES |
dc.rights | openAccess | es_ES |
dc.title | Role of crystal size on swing-effect and adsorption induced structure transition of ZIF-8 | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1039/C6DT00565A | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1039/C6DT00565A | es_ES |
dc.rights.license | http://creativecommons.org/licenses/by/3.0/ | es_ES |
dc.relation.csic | Sí | es_ES |
oprm.item.hasRevision | no ko 0 false | * |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.grantfulltext | open | - |
item.openairetype | artículo | - |
item.fulltext | With Fulltext | - |
item.languageiso639-1 | en | - |
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Role_crystal_Tian.pdf | 5,51 MB | Adobe PDF | Visualizar/Abrir |
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