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Título: | Vibrational transition rule during a through-bond electron transfer process |
Autor: | Monturet, Serge; Kepenekian, M. CSIC ORCID; Robles, Roberto CSIC ORCID ; Lorente, Nicolás CSIC ORCID CVN; Joachim, Christian | Fecha de publicación: | 2013 | Editor: | Elsevier | Citación: | Chemical Physics Letters 567: 1- 5 (2013) | Resumen: | The transition rule governing the inelastic excitations of molecular vibrations occurring during a molecular through-state electron transfer process is presented. Using an effective Hamiltonian model, it is shown that the quantum time oscillation of the intermediate electronic state population triggers this transition. Its corresponding quantum oscillation frequency has to be equal to a quantum of vibration. This transition rule is extended to the full spectrum of a quantum vibrator. This new transition rule is expected to be robust when electronically coupling the molecule to the metallic pads of a voltage-biased tunnel junction. © 2013 Elsevier B.V. All rights reserved. | Versión del editor: | http://dx.doi.org/10.1016/j.cplett.2013.02.057 | URI: | http://hdl.handle.net/10261/99679 | DOI: | 10.1016/j.cplett.2013.02.057 | Identificadores: | doi: 10.1016/j.cplett.2013.02.057 issn: 0009-2614 |
Aparece en las colecciones: | (CIN2) Artículos |
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Vibrational transition rule.pdf | 212,92 kB | Adobe PDF | Visualizar/Abrir |
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