English   español  
Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/99576
COMPARTIR / IMPACTO:
Estadísticas
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
Título

Deep eutectic assisted synthesis of carbon adsorbents highly suitable for low-pressure separation of CO2–CH4 gas mixtures

AutorGutiérrez, María C. ; Carriazo, Daniel ; Ovín Ania, María Concepción ; Parra Soto, José Bernardo ; Ferrer, M. Luisa ; Monte, Francisco del
Fecha de publicaciónjun-2012
EditorRoyal Society of Chemistry (Great Britain)
CitaciónEnergy and Environmental Science 5: 8699-8707 (2012)
ResumenIonic liquids and deep eutectic solvents (a new class of ionic liquids obtained by complexation of quaternary ammonium salts with hydrogen bond donors such as acids, amines, and alcohols among others) have been recently used as solvents and even as precursors in the synthesis of carbonaceous materials. The use of long-alkyl-chain derivatives of ionic liquids that, playing the role of structure directing agents, were capable of designing the mesoporous structure of the resulting carbons is of particular interest. Meanwhile, deep eutectic solvents proved efficient in tailoring the structure comprised between large mesopores and small macropores, but the control over the smaller ones (e.g. small mesopores and micropores) is still a challenge as compared to ILs. Herein, we have used deep eutectic solvents composed of resorcinol, 4-hexylresorcinol and tetraethylammonium bromide for the synthesis of carbon monoliths with a tailor-made narrow microporosity. Behaving as molecular sieves, these carbons exhibited not only good capacities for CO2 adsorption (up to 3 mmol g−1) but also an outstanding – especially at low pressures – CO2–CH4 selectivity.
Versión del editorhttp://dx.doi.org/10.1039/C2EE22029F
URIhttp://hdl.handle.net/10261/99576
DOI10.1039/C2EE22029F
ISSN1754-5692
Aparece en las colecciones: (INCAR) Artículos
Ficheros en este ítem:
Fichero Descripción Tamaño Formato  
Deep_eutectic_Ania.pdf798,75 kBAdobe PDFVista previa
Visualizar/Abrir
Mostrar el registro completo
 

Artículos relacionados:


NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.