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Effect of dispersion forces on the capillary-wave fluctuations of liquid surfaces

AutorChacón, Enrique ; Fernández, Eva M. ; Tarazona, Pedro
Fecha de publicación2014
EditorAmerican Physical Society
CitaciónPhysical Review E 89: 042406 (2014)
ResumenWe present molecular dynamics evidence for the nonanalytic effects of the long-range dispersion forces on the capillary waves fluctuations of a Lennard-Jones liquid surface. The results of the intrinsic sampling method, for the analysis of the instantaneous interfacial shape, are obtained in large systems for several cut-off distances of the potential tail, and they show good agreement with the theoretical prediction by Napiórkowski and Dietrich, based on a density functional analysis. The enhancement of the capillary waves is quantified to be within 1% for a simple liquid near its triple point. © 2014 American Physical Society.
Versión del editorhttp://dx.doi.org/10.1103/PhysRevE.89.042406
URIhttp://hdl.handle.net/10261/98822
DOI10.1103/PhysRevE.89.042406
Identificadoresdoi: 10.1103/PhysRevE.89.042406
e-issn: 1550-2376
issn: 1539-3755
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