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Dual role of copper on the reactivity of activated carbons from coal and lignocellulosic precursors

AutorHaro Remón, Marta ; Ruiz Bobes, Begoña ; Andrade, Marta; Mestre, Ana S.; Parra Soto, José Bernardo ; Carvalho, A.P.; Ovín Ania, María Concepción
Palabras claveActivated carbon
Copper
Isothermal gasification
Fecha de publicaciónmay-2012
EditorElsevier
CitaciónMicroporous and Mesoporous Materials 154: 68-73 (2012)
ResumenThe synthesis of copper-doped activated carbons from different origin (i.e., lignocellulosic and bituminous coal) by a wet impregnation and low temperature calcination procedure has been explored, as well as the role of copper particles on the physicochemical and structural features of the resulting materials. The textural characterization and isothermal reactivity analysis of the pristine and doped activated carbons have shown that the role of copper during the calcination step strongly depended on the nature of the carbon matrix. Copper impregnation of a coal-derived activated carbon catalyzed the air gasification of the material at a very low temperature (i.e., 325 °C), bringing about the development of microporosity on the doped carbon. In contrast, when copper was immobilized on a lignocellulose-derived activated carbon, the metallic species act as combustion retardant during the calcination step, protecting the carbon matrix during the catalytic gasification. In both cases, the resulting materials displayed a homogenous distribution of copper within the carbon matrix, while preserving large textural properties.
Versión del editorhttp://dx.doi.org/10.1016/j.micromeso.2011.07.005
URIhttp://hdl.handle.net/10261/98694
DOI10.1016/j.micromeso.2011.07.005
ISSN1387-1811
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