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Title

Protonolysis of Fe-C bonds of a diiminopyridineiron(II) dialkyl complex by acids of different strengths: Influence of monoanionic ligands on the spectroscopic properties of diiminopyiridine-FeY2 complexes

AuthorsCartes, M. Ángeles ; Palma, Pilar ; Sandoval, John J. ; Cámpora, Juan ; Álvarez, Eleuterio
KeywordsIron
Alkyl complexes
Olefin polymerization.
2,6-bisiminopyridine ligands
Issue Date2014
PublisherElsevier
CitationInorganica Chimica Acta 412: 73- 78 (2014)
AbstractThe reaction of the dialkyliron complex [Fe(CH2SiMe 3)2(MesBIP)] (MesBIP = 2,6-bis((N-mesityl)acetimidoyl)pyridine) with protic acids (HY) of different strengths (Y = C6F5O, CF3CO2, Cl, CF3SO3) invariably leads to the cleavage of both Fe-C bonds, independent of the Fe/HY ratio used (either 1:2 or 1:1), affording the corresponding complexes [FeY2(MesBIP)]. Relevant spectroscopic features of these compounds, such as paramagnetic 1H NMR shifts and UV-Vis absorption bands, exhibit a marked dependence on the nature of Y. © 2013 Elsevier B.V. All rights reserved.
URIhttp://hdl.handle.net/10261/98219
DOIhttp://dx.doi.org/10.1016/j.ica.2013.11.028
Identifiersdoi: 10.1016/j.ica.2013.11.028
issn: 0020-1693
Appears in Collections:(IIQ) Artículos
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