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Discovery of anion-π interactions in the recognition mechanism of inorganic anions by 1,2,3-triazolium rings

AuthorsCaballero, A.; Zapata, Fabiola; Gonzalez, L.; Molina, P.; Alkorta, Ibon ; Elguero, José
Issue Date2014
CitationCHEM. COMMUN. 50: 4680- 4682 (2014)
AbstractA bis(triazolium)-based receptor designed for anion recognition is presented. NMR spectroscopic data indicate that one triazolium ring is acting as a hydrogen bond donor, whereas the second triazolium ring behaves as an anion-π receptor. The simultaneous presence of two noncovalent interactions allows us to achieve a highly selective binding of the hydrogenpyrophosphate anion. This journal is © the Partner Organisations 2014.
Identifiersdoi: 10.1039/c4cc00169a
issn: 1359-7345
e-issn: 1364-548X
Appears in Collections:(IQM) Artículos
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