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Highly enantioselective hydrogenation of 1-alkylvinyl benzoates: A simple, nonenzymatic access to chiral 2-alkanols

AuthorsKleman, Patryk Artur; González-Liste, Pedro J.; García-Garrido, Sergio E.; Cadierno, Victorio; Pizzano, Antonio
Asymmetric hydrogenation
Issue Date2013
PublisherJohn Wiley & Sons
CitationChemistry - A European Journal 19: 16209- 16212 (2013)
AbstractGoing chiral! Highly enantioselective catalytic hydrogenations of enol esters 1 by using a Rh catalyst bearing a POP ligand are described (see scheme; NBD=norbornadiene). The catalytic system has a broad scope and allows the preparation of a wide range of chiral esters 2 bearing diverse alkyls or a benzyl group with high enantioselectivities. These esters can easily be converted in highly enantioenriched 2-alkanols. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Identifiersdoi: 10.1002/chem.201303500
issn: 0947-6539
Appears in Collections:(IIQ) Artículos
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