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Experimental evidences in favour of the hydroxylamine→nitrene-water tautomerization on the coordination sphere of IrIII centres

AuthorsCristóbal, Crispín; López-Serrano, Joaquín ; Lozano-Vila, Ana M. ; Paneque, Margarita ; Poveda, Manuel L.; Vattier, Florencia ; Vivancos, Ángela; Álvarez, Eleuterio
Issue Date2013
PublisherJohn Wiley & Sons
CitationChemistry - A European Journal 19: 10128- 10131 (2013)
AbstractAnd, to round off. A series of IrIII 5-membered metallacycles with an Ir-CH2 bond, react with aq. NH2OH with formation of hydride 6-membered iridacyclic complexes, which contain an Ir-NHï£CH- imine functionality (see scheme). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Identifiersdoi: 10.1002/chem.201300624
issn: 0947-6539
Appears in Collections:(IIQ) Artículos
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