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dc.contributor.authorSantos, Laura L.-
dc.contributor.authorPaneque, Margarita-
dc.contributor.authorMereiter, Kurt-
dc.identifierdoi: 10.1107/S1600536813007344-
dc.identifierissn: 1600-5368-
dc.identifier.citationActa Crystallographica Section E: Structure Reports Online 69: m224- m225 (2013)-
dc.description.abstractIn the title compound, [Ir(C15H22BN 6)(C8H7O)Cl]·CHCl3, the Ir atom is formally trivalent and is coordinated in a slightly distorted octahedral geometry by three facial N atoms, one C atom, one O atom and one Cl atom. The Ir=Ccarbene bond is strong and short and exerts a notable effect on the trans-Ir-N bond, which is about 0.10 Å longer than the two other Ir-N bonds. The chloroform solvent molecule is anchored via a weak C-H⋯Cl hydrogen bond to the Cl atom of the Ir complex molecule. In the crystal, the constituents adopt a layer-like arrangement parallel to (010) and are held together by weak intermolecular C-H⋯Cl hydrogen bonds, as well as weak Cl⋯Cl [3.498 (2) Å] and Cl⋯π [3.360 (4) Å] interactions. A weak intramolecular C-H⋯O hydrogen bond is also observed.-
dc.publisherBlackwell Publishing-
dc.subjectR factor = 0.028-
dc.subjectMean (C–C) = 0.005 A˚-
dc.subjectwR factor = 0.071-
dc.subjectData-to-parameter ratio = 23.6.-
dc.subjectT = 173 K-
dc.subjectKey indicators: single-crystal X-ray study-
dc.titleChlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl) hydroborato]iridium(III) chloroform monosolvate-
dc.description.versionPeer Reviewed-
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