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Título: | Chlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl) hydroborato]iridium(III) chloroform monosolvate |
Autor: | Santos, Laura L. CSIC ORCID; Paneque, Margarita CSIC ORCID; Mereiter, Kurt | Palabras clave: | R factor = 0.028 Mean (C–C) = 0.005 A˚ wR factor = 0.071 Data-to-parameter ratio = 23.6. T = 173 K Key indicators: single-crystal X-ray study |
Fecha de publicación: | 2013 | Editor: | Blackwell Publishing | Citación: | Acta Crystallographica Section E: Structure Reports Online 69: m224- m225 (2013) | Resumen: | In the title compound, [Ir(C15H22BN 6)(C8H7O)Cl]·CHCl3, the Ir atom is formally trivalent and is coordinated in a slightly distorted octahedral geometry by three facial N atoms, one C atom, one O atom and one Cl atom. The Ir=Ccarbene bond is strong and short and exerts a notable effect on the trans-Ir-N bond, which is about 0.10 Å longer than the two other Ir-N bonds. The chloroform solvent molecule is anchored via a weak C-H⋯Cl hydrogen bond to the Cl atom of the Ir complex molecule. In the crystal, the constituents adopt a layer-like arrangement parallel to (010) and are held together by weak intermolecular C-H⋯Cl hydrogen bonds, as well as weak Cl⋯Cl [3.498 (2) Å] and Cl⋯π [3.360 (4) Å] interactions. A weak intramolecular C-H⋯O hydrogen bond is also observed. | URI: | http://hdl.handle.net/10261/97368 | DOI: | 10.1107/S1600536813007344 | Identificadores: | doi: 10.1107/S1600536813007344 issn: 1600-5368 |
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