English   español  
Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/97365
Compartir / Impacto:
Estadísticas
Add this article to your Mendeley library MendeleyBASE
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Título

(Butane-1,4-diyl)(trimethylphosphane-κP)[tris(3,5-dimethylpyrazol-1- yl-κN 2)hydroborato]iridium(III)

AutorGómez, Margarita ; Santos, Laura L. ; Paneque, Margarita ; Mereiter, Kurt
Palabras claveData-to-parameter ratio = 24.7.
Single-crystal X-ray study
wR factor = 0.040
R factor = 0.017
Disorder in main residue
mean (C–C) = 0.003 A°
T = 173 K
Fecha de publicación2013
EditorBlackwell Publishing
CitaciónActa Crystallographica Section E: Structure Reports Online 69: m234- m235 (2013)
ResumenIn the mononuclear title iridium(III) complex, [Ir(C4H 8)(C15H22BN6)(C3H 9P)], which is based on the [tris(3,5-dimethylpyrazol-1-yl) hydroborato]iridium moiety, Ir[TpMe2], the IrIII atom is coordinated by a chelating butane-1,4-diyl fragment and a trimethylphosphane ligand in a modestly distorted octahedral coordination environment formed by three facial N, two C and one P atom. The iridium-butane-1,4-diyl ring has an envelope conformation. This ring is disordered because alternately the second or the third C atom of the butane-1,4-diyl fragment function as an envelope flap atom (the occupancy ratio is 1:1). In the crystal, molecules are organized into densely packed columns extending along [101]. Coherence between the molecules is essentially based on van der Waals interactions.
URIhttp://hdl.handle.net/10261/97365
DOI10.1107/S1600536813008040
Identificadoresdoi: 10.1107/S1600536813008040
issn: 1600-5368
Aparece en las colecciones: (IIQ) Artículos
Ficheros en este ítem:
Fichero Descripción Tamaño Formato  
gk2565.pdf503,36 kBAdobe PDFVista previa
Visualizar/Abrir
Mostrar el registro completo
 

Artículos relacionados:


NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.