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Building a parent iridabenzene structure from acetylene and dichloromethane on an iridium center

AuthorsVivancos, Ángela; Paneque, Margarita ; Poveda, Manuel L.; Álvarez, Eleuterio
Issue Date2013
PublisherJohn Wiley & Sons
CitationAngewandte Chemie - International Edition 52: 10068- 10071 (2013)
AbstractParenthood: The reaction of [TpIr(C2H4)2] (1) (Tp=hydrotris(pyrazolyl)borate) with acetylene in CH2Cl 2 affords a 1:1 mixture of the >parent> metallabenzene 2 (that is, all the ring carbon centers are CH units) and the ß-Cl substituted vinyl species 3. Generation of 2 is by the coupling of an iridacyclopentadiene (formed from two acetylene molecules at the Ir center) with the dichloromethane-derived chlorocarbene >:C(H)Cl> and a subsequent ¿-Cl elimination event. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Identifiersdoi: 10.1002/anie.201305319
issn: 1433-7851
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