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Title

Axially chiral triazoloisoquinolin-3-ylidene ligands in gold(I)-catalyzed asymmetric intermolecular (4 + 2) cycloadditions of allenamides and dienes

AuthorsFrancos, J.; Grande-Carmona, F. ; Faustino, H.; Iglesias-Sigüenza, Javier; Díez, Elena; Alonso, Inés; Lassaletta, José M. ; López, F.; Mascareñas, José L.
Issue Date2012
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 134: 14322- 14325 (2012)
AbstractThe first highly enantioselective intermolecular (4 + 2) cycloaddition between allenes and dienes is reported. The reaction provides good yields of optically active cyclohexenes featuring diverse substitution patterns and up to three stereocenters. Key to the success of the process is the use of newly designed axially chiral N-heterocyclic carbene-gold catalysts. © 2012 American Chemical Society.
URIhttp://hdl.handle.net/10261/96604
DOI10.1021/ja3065446
Identifiersdoi: 10.1021/ja3065446
issn: 0002-7863
Appears in Collections:(IIQ) Artículos
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