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Title

Gold/acid-co-catalyzed direct microwave-assisted synthesis of fused azaheterocycles from propargylic hydroperoxides

AuthorsAlcaide, Benito ; Almendros, Pedro ; Quirós, M. Teresa
Keywordsamines
alkynes
gold
heterocycles
peroxides
Issue Date2014
PublisherJohn Wiley & Sons
CitationChemistry - A European Journal 20: 3384- 3393 (2014)
AbstractThe gold-acid-co-catalyzed synthesis of nine series of fused azaheterocycles with structural diversity starting from the same synthons as readily available propargylic hydroperoxides and aromatic amines has been achieved. The overall tandem process consists in a gold-catalyzed hydroperoxide rearrangement/Michael reaction followed by a final acid-catalyzed cyclization.
URIhttp://hdl.handle.net/10261/96305
DOI10.1002/chem.201304509
Identifiersdoi: 10.1002/chem.201304509
issn: 1521-3765
e-issn: 1521-3765
Appears in Collections:(IQOG) Artículos
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