English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/95572
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:


Tailoring two polymorphs of LiFePO4 by efficient microwave-assisted synthesis: A combined experimental and theoretical study

AuthorsZeng, G.; Caputo, Riccarda; Carriazo, Daniel ; Luo, Li; Niederberger, M.
KeywordsMicrowave synthesis
Lithium-ion batteries
Issue Date2013
PublisherAmerican Chemical Society
CitationChemistry of Materials 25(17): 3399-3407 (2013)
AbstractLiFePO4 typically crystallizes in the olivine-type phase (denoted as α-phase hereafter). When high pressure (65 kbar) and elevated temperature (900 C) are applied, the α-LiFePO4 transforms into a high-pressure phase (denoted as β-phase hereafter). Here, we report a facile approach to directly tailor the two polymorphs of LiFePO4 in a controlled way under mild conditions. Employing a microwave-assisted nonaqueous route, highly crystalline LiFePO4 with either α- or β-phase can be efficiently synthesized within 3 min, by simply tuning the ratio of the solvents, benzyl alcohol, and 2-pyrrolidinone. The resulting β-LiFePO4 particles exhibit a hierarchical self-assembled bow-tie-like microstructure, whereas the α-phase consists of nanoplates. In addition, the β-phase irreversibly transforms into the α-phase upon heat treatment without alteration of the morphology. After carbon-coating, α-LiFePO4 and phase-transformed β-LiFePO4, that is, α-LiFePO4 with the hierarchical morphology of the β-phase, exhibit excellent electrochemical performance, whereas pristine β-LiFePO4 displays unfavorable properties. Density functional total energy calculations are performed to get the relative energies and lattice stability of the two phases. A qualitative understanding of the poor electrochemical performance of the β-phase can be deduced from the molecular dynamics of the mobile Li ions in both structures. © 2013 American Chemical Society.
Identifiersdoi: 10.1021/cm400995g
issn: 0897-4756
e-issn: 1520-5002
Appears in Collections:(ICMM) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf15,38 kBAdobe PDFThumbnail
Show full item record
Review this work

Related articles:

WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.