Please use this identifier to cite or link to this item:
http://hdl.handle.net/10261/9459
Share/Export:
![]() ![]() |
|
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Title: | Asymmetric synthesis of long chain α-methyl-β-thiotrifluoromethyl ketones employing the SAMP-/RAMP-hydrazone alkylation methodology |
Authors: | Muñoz, Lourdes CSIC ORCID; Bosch, María Pilar CSIC; Guerrero, Ángel CSIC ORCID | Keywords: | α-methylation β-thiotrifluoromethyl ketones Optically active compounds Pheromone antagonists |
Issue Date: | 19-Mar-2007 | Publisher: | Elsevier | Citation: | Tetrahedron: Asymmetry 18(5): 651-658 (2007) | Abstract: | The enantioselective synthesis of both enantiomers of (Z)-1,1,1-trifluoro-3-methyl-4-thia-13-octadecen-2-one and (Z)-1,1,1- trifluoro-3-methyl-4-thia-13-hexadecen-2-one (ee ≥ 90%), potential inhibitors of the pheromone action of two major maize pests Sesamia nonagrioides and Ostrinia nubilalis, is described. The key step is based upon a stereoselective alkylation with methyl iodide using the SAMP-/RAMP-chiral auxiliary methodology, followed by deprotection under non-racemization conditions. | Description: | 8 pages, 1 figure.-- Printed version published on Mar 30, 2007. | Publisher version (URL): | http://dx.doi.org/10.1016/j.tetasy.2007.02.022 | URI: | http://hdl.handle.net/10261/9459 | DOI: | 10.1016/j.tetasy.2007.02.022 | ISSN: | 0957-4166 | E-ISSN: | 1362-511X |
Appears in Collections: | (IQAC) Artículos |
Show full item record
Review this work
SCOPUSTM
Citations
4
checked on May 13, 2022
WEB OF SCIENCETM
Citations
2
checked on May 14, 2022
Page view(s)
361
checked on May 21, 2022
Google ScholarTM
Check
Altmetric
Dimensions
WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.