Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/94338
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Title

Heterobimetallic sodium–lithium based metal–organic framework showing the β-cristobalite topology and having high permanent porosity

AuthorsMedina, Manuela E. CSIC; Millange, Franck
KeywordsMetal–organic frameworks
Sodium
Adsorption
Lithium
Zeotypes
Issue Date2013
PublisherWiley-VCH
CitationEuropean Journal of Inorganic Chemistry(7): 1138-1141 (2013)
AbstractThe solvothermal synthesis of a novel mixed-s-block metal–organic framework is described, with crystallization brought about by use of the sodium salt of the benzo-(1,2;3,4;5,6)-tris(thiophene-2′-carboxylate) linker in combination with a lithium salt. The structure of the material was determined by single-crystal X-ray diffraction, which reveals an expanded version of the β-cristobalite topology, with supertetrahedral building units made up of clusters of sodium and lithium ions. Outgassing under vacuum gives permanent porosity to the solid structure with a BET surface area of 1191 m2 g–1 measured by nitrogen adsorption.
URIhttp://hdl.handle.net/10261/94338
DOI10.1002/ejic.201201508
Identifiersdoi: 10.1002/ejic.201201508
issn: 1434-1948
e-issn: 1099-0682
Appears in Collections:(ICMM) Artículos

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