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Título: | Oxygen-functionalized highly mesoporous carbon xerogel based catalysts for direct methanol fuel cell anodes |
Autor: | Alegre Gresa, Cinthia CSIC ORCID; Gálvez Parruca, María Elena CSIC ORCID; Baquedano, Estela CSIC ORCID; Moliner Álvarez, Rafael CSIC ORCID; Pastor Tejera, Elena; Lázaro Elorri, María Jesús CSIC ORCID | Fecha de publicación: | 30-may-2013 | Editor: | American Chemical Society | Citación: | Journal of Physical Chemistry C 117(25): 13045-13058 (2013) | Resumen: | PtRu catalysts were prepared using a highly mesoporous carbon xerogel submitted to different oxygen functionalization treatments: diluted and concentrated nitric acid as well as gas-phase 5% O2−N2 oxidation. Catalysts with 20 wt % loading and equimolar Pt:Ru metallic phase were prepared using an impregnation procedure involving chemical reduction with formic acid. The so-obtained carbon materials, as well as the different catalysts synthesized, were characterized by means of N2 physisorption, temperature-programmed desorption (TPD), X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). Cyclic voltammetry and chronoamperometry were performed to study their activity toward carbon monoxide and methanol oxidation. Functionalization of the carbon support was found to play a definitive role in the interaction between carbon material and the active phase, determining metallic dispersion, alloying degree, and reduction extent. The activity of the catalysts in methanol electro-oxidation was directly related to the metal oxidation state and alloying degree. | Descripción: | 14 páginas.- 8 figuras en color.- 6 tablas. | Versión del editor: | http://dx.doi.org/10.1021/jp400824n | URI: | http://hdl.handle.net/10261/93840 | DOI: | 10.1021/jp400824n | ISSN: | 1932-7447 | E-ISSN: | 1932-7455 |
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