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Charge transfer-assisted self-limited decyanation reaction of TCNQ-type electron acceptors on Cu(100)

AuthorsMartín, Nazario; Gallego, José M. ; Miranda, Rodolfo; Otero, Roberto
Issue Date2014
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 50(7): 833-835 (2014)
AbstractTCNQ derivatives adsorbed on a metal surface undergo a self-limited decyanation reaction that only affects two out of the four cyano groups in the molecule. Combined Scanning Tunneling Microscopy/X-ray Photoelectron Spectroscopy experiments and Density Functional Theory calculations relate the self-limiting behavior to the transfer of electrons from the metal to the molecule. This journal is © The Royal Society of Chemistry.
Identifiersdoi: 10.1039/c3cc45791e
issn: 1359-7345
e-issn: 1364-548X
Appears in Collections:(ICMM) Artículos
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