English   español  
Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/93315
COMPARTIR / IMPACTO:
Estadísticas
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
Título

Homogenous thin layer coated graphene via one pot reaction with multidentate thiolated PMMAs

AutorLiras, Marta ; García Ballesteros, Olga; Quijada-Garrido, Isabel ; Ellis, Gary James ; Salavagione, Horacio J.
Fecha de publicación2014
CitaciónJournal of Materials Chemistry C 2: 1723- 1729 (2014)
ResumenA novel strategy for the covalent coverage of the graphene surface with brush-like PMMA-SH or multidentate P(MMA-co-SEMA) copolymers by the thiol-ene click reaction is reported. The new graphene@polymer materials were characterized by FTIR and Raman spectroscopy, thermogravimetric analysis, and AFM, TEM and SEM. AFM images and 2D Raman mapping of the D/G ratio of CVD-graphene covered with brush and multidentate polymers clearly illustrated a more homogeneous modification in the case of the latter. The multidentate-copolymer forms a thin layer covering the graphene surface, contrary to the case for typical polymer brushes. It also displays good conductivity values on the order of the initial unmodified graphene material suggesting that the covalent modification with the polymer is not detrimental to the sp2 network. A conductivity of ∼2 × 10-3 S cm-1 was achieved in a graphene-based PMMA nanocomposite using graphene@P(MMA-co-SEMA) as a filler, highlighting the importance of engineering the graphene-polymer interface through multidentate copolymer functionalization of graphene. © 2014 The Royal Society of Chemistry.
URIhttp://hdl.handle.net/10261/93315
DOI10.1039/c3tc32136c
Identificadoresdoi: 10.1039/c3tc32136c
issn: 2050-7534
Aparece en las colecciones: (ICTP) Artículos
Ficheros en este ítem:
Fichero Descripción Tamaño Formato  
accesoRestringido.pdf15,38 kBAdobe PDFVista previa
Visualizar/Abrir
Mostrar el registro completo
 


NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.