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Experimental and theoretical determination of rotational-translational state-to-state rate constants for N2:He collisions at low temperature (3<T<20 K)

AutorMaté, Belén ; Thibault, Franck; Ramos, Ángel ; Tejeda, Guzmán ; Fernández Sánchez, José María ; Montero, Salvador
Palabras claveNitrogen
Vibrational states
Ground states
Helium neutral atoms
Atom-molecule collisions
Fecha de publicación8-mar-2003
EditorAmerican Institute of Physics
CitaciónJ. Chem. Phys. 118(10): 4477-4486 (2003)
ResumenWe present an experimental determination of state-to-state rotational–translational (RT) rate constants of N2:He collisions in the vibrational ground state as a function of temperature in the range 3<T<20 K. Raman spectroscopy in supersonic expansions of N2/He mixtures is used to determine the primary data that, together with the N2:N2 state-to-state RT rates previously determined [Ramos et al., Phys. Rev. A 66, 022702 (2002)], are needed to solve the master equation according to a procedure that does not impose any particular scaling law. We also report first principle calculations of the N2:He state-to-state RT rate constants performed using the full three-dimensional potential energy surface of Reid et al. [J. Chem. Phys. 107, 2329 (1997)], in the 3<T<300 K temperature range. The coupled-channel method, and the coupled-states approximation, were applied in the low (0–610 cm–1) and in the high (610–1500 cm–1) energy limits, respectively. A good agreement between theoretical and experimental results is found in the temperature range where comparison is possible.
Descripción10 pages, 7 figures.-- PACS nr.: 34.50.Fa.
Versión del editorhttp://dx.doi.org/10.1063/1.1543945
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