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Platinum-catalyzed divergent reactivity of α-hydroxyallenes: Synthesis of dihydrofurans and α,β-unsaturated ketones

AuthorsAlcaide, Benito ; Almendros, Pedro ; Fernández, I.; Campo, T. M. D.; Naranjo, T.
Issue Date2013
PublisherJohn Wiley & Sons
CitationAdvanced Synthesis and Catalysis 355: 2681- 2685 (2013)
Abstractα-Allenols were catalytically transformed into dihydrofurans in the presence of platinum dichloride. Notably, using platinum dichloride along with silver triflate as the catalytic system, α,β-unsaturated ketones were obtained. Therefore, the role of the silver salt may not just consist in the activation of the platinum precatalyst. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Identifiersdoi: 10.1002/adsc.201300413
issn: 1615-4150
e-issn: 1615-4169
Appears in Collections:(IQOG) Artículos
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