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Title

On the fine structure of shish-kebabs in injection molded polyethylene.

AuthorsMartínez-Salazar, Javier ; García-Ramos, José Vicente ; Petermann, J.
KeywordsSAXS at elevated temperatures.
Shish-kebab morphology
Molecular connectivity
Issue Date1993
PublisherTaylor & Francis
CitationInternational Journal of Polymeric Materials 21: 111-121 (1993)
AbstractThe fine structure of melt-crystallized shish-kebabs is investigated by means of TEM, SAXS, DSC and RS. In addition to the well known two morphological entities (shish and kebab), a third entity called “transitional zone” has been detected by TEM and two independent SAXS maxima. The transitional zone is characterized by a crystal morphology somewhere in between the shish and kebab crystals and a comparatively high connectivity of molecules along those crystals. In situ SAXS experiments at elevated temperatures reveal the change of the size of this zone with crystallization conditions. © 1993
URIhttp://hdl.handle.net/10261/88945
DOI10.1080/00914039308012038
Identifiersdoi: 10.1080/00914039308012038
issn: 0091-4037
Appears in Collections:(CFMAC-IEM) Artículos
(CFMAC-IO) Artículos
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