English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/85358
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE
Exportar a otros formatos:

DC FieldValueLanguage
dc.contributor.authorHashem, Emtithal-
dc.contributor.authorLorusso, Giulia-
dc.contributor.authorEvangelisti, Marco-
dc.contributor.authorMcCabe, Thomas-
dc.contributor.authorSchulzke, Carola-
dc.contributor.authorPlatts, James A.-
dc.contributor.authorBaker, Robert J.-
dc.date.accessioned2013-10-30T11:51:32Z-
dc.date.available2013-10-30T11:51:32Z-
dc.date.issued2013-09-
dc.identifier.citationDalton Transactions 42(41): 14677-14680 (2013)es_ES
dc.identifier.issn1477-9226-
dc.identifier.urihttp://hdl.handle.net/10261/85358-
dc.description.abstractThe solid-state structure of the known complex [Et4N][U(NCS)5(bipy)2] has been re-determined and a detailed spectroscopic and magnetic study has been performed in order to confirm the oxidation states of both metal and bipy ligand. Electronic absorption and infrared spectroscopy suggest that the uranium is in its +4 oxidation state and this has been corroborated by emission spectroscopy and variable temperature magnetic measurements, as well as theoretical calculations. Therefore the bipy ligands are neutral, innocent ligands and not, as would be inferred from just a solid state structure, radical anions.es_ES
dc.description.sponsorshipWe thank TCD and MINECO (MAT2012-38318-C03), and EC for a Marie Curie-IEF (PIEF-GA-2011-299356 to GL) for funding this work.es_ES
dc.language.isoenges_ES
dc.publisherRoyal Society of Chemistry (UK)es_ES
dc.relation.isversionofPreprint-
dc.rightsopenAccesses_ES
dc.titleFingerprinting the oxidation state of U(IV) by emission spectroscopyes_ES
dc.typeartículoes_ES
dc.identifier.doi10.1039/C3DT52151F-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1039/C3DT52151Fes_ES
dc.identifier.e-issn1477-9234-
dc.contributor.funderEuropean Commission-
dc.contributor.funderMinisterio de Economía y Competitividad (España)-
dc.relation.csic-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
Appears in Collections:(ICMA) Artículos
Files in This Item:
File Description SizeFormat 
Fingerprinting.pdf300,31 kBAdobe PDFThumbnail
View/Open
Show simple item record
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.