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Título:	Simplifying the conductance profiles of molecular junctions: The use of the trimethylsilylethynyl moiety as a molecule-gold contact
Autor:	Martín, Santiago CSIC ORCID; García-Suárez, Víctor M. CSIC ORCID ; Cea, Pilar CSIC ORCID; Low, Paul J.
Fecha de publicación:	2013
Editor:	Royal Society of Chemistry (UK)
Citación:	Dalton Transactions 42(2): 338-341 (2013)
Resumen:	Conductance across a metal\|molecule\|metal junction is strongly influenced by the molecule-substrate contacts, and for a given molecular structure, multiple conductance values are frequently observed and ascribed to distinct binding modes of the contact at each of the molecular termini. Conjugated molecules containing a trimethylsilylethynyl terminus, -Câ‰¡CSiMe 3 give exclusively a single conductance value in I(s) measurements on gold substrates, the value of which is similar to that observed for the same molecular backbone with thiol and amine based contacting groups when bound to under-coordinated surface sites. © 2013 The Royal Society of Chemistry.
Descripción:	4 páginas, 3 figuras.-- et al.
Versión del editor:	http://dx.doi.org/10.1039/c2dt31825c
URI:	http://hdl.handle.net/10261/82988
DOI:	10.1039/c2dt31825c
Identificadores:	doi: 10.1039/c2dt31825c issn: 1477-9226 e-issn: 1477-9234
Aparece en las colecciones:	(ICMA) Artículos (CINN) Artículos

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Simplifying the conductance profiles of molecular junctions: The use of the trimethylsilylethynyl moiety as a molecule-gold contact