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Title

Functionalization of Carbon Nanotubes via Nitrogen Glow Discharge

AuthorsKhare, Bishun; Wilhite, Patrick; Tran, Benjamin; Teixeira, Elico; Fresquez, Kenneth; Nna Mvondo, Delphine ; Bauschlicher, Charles; Meyyappan, M.
KeywordsSingle-wall carbon nanotubes (SWCNTs)
Nitrogen functionalization
Distance to the discharge source
Nanotube characterization via spectroscopy
Issue Date15-Nov-2005
PublisherAmerican Chemical Society
CitationJ. Phys. Chem. B 109 (49): 23466 -23472 (2005)
AbstractWe have exposed single-wall carbon nanotubes (SWCNTs) to microwave-generated N2 plasma with the aim to functionalize the nanotubes. The results strongly depend on the distance between the discharge source and the sample, since nitrogen atoms generated can be lost due to recombination. No functionalization was observed when this distance was 7.0 cm. At intermediate distances (2.5 cm), the incorporation of nitrogen and oxygen onto the SWCNT was observed, while, at short distances (1 cm), products containing C≡N were also observed.
Description7 pages, 9 figures.-- PMID: 16375320 [PubMed].
Publisher version (URL)http://dx.doi.org/10.1021/jp0537254
URIhttp://hdl.handle.net/10261/8221
DOI10.1021/jp0537254
ISSN1520-6106
Appears in Collections:(CAB) Comunicaciones congresos
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