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High-resolution stimulated Raman-Spectrum of Ethane ((C2H6)-C-12) in the region of the C-H symmetrical stretching

AuthorsAbad, Laura ; Bermejo, Dionisio ; Cancio, P. ; Domingo, Concepción ; Herrero, Víctor J. ; Santos, Julio ; Tanarro, Isabel ; Montero, Salvador
Issue Date1994
PublisherJohn Wiley & Sons
CitationJournal of Raman Spectroscopy 25: 589- 597 (1994)
AbstractThe high-resolution (ca. 0.008 cm−1) stimulated Raman spectrum of the strongly perturbed C[BOND]H symmetric stretching region of 12C2H6 at room temperature and at a rotational temperature of ca. 30 K, achieved in a free supersonic jet expansion chamber, is reported. The spectrum is tentatively analysed and assigned in terms of a simplified vibration-torsion–rotation Hamiltonian. Besides the already known strong Fermi resonance, several Coriolis torsional interactions are identified as the major perturbations in this spectral region. © 1994 John Wiley & Sons, Ltd.
Description22 pags.; 8 figs.; 3 tabs.
Publisher version (URL)http://dx.doi.org/10.1002/jrs.1250250720
Identifiersdoi: 10.1002/jrs.1250250720
issn: 0377-0486
Appears in Collections:(CFMAC-IEM) Artículos
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