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Title

Laser Stark spectroscopy of silyl fluoride in the 10-μm region: Analysis of the ν2 and ν5 bands

AuthorsEscribano, Rafael ; Butcher, R.J.
Issue Date1983
PublisherAcademic Press
CitationJournal of Molecular Spectroscopy 99: 450- 475 (1983)
AbstractThe v2 = 1 and v5 = 1 states of silyl fluoride are strongly mixed by Coriolis coupling. About 1100 Stark tuned resonances were measured in these bands using 12CO2 and 13CO2 lasers. These data were combined with 13 new millimeterwave measurements and 900 Fourier transform infrared measurements in a suitable model. Apart from the main Coriolis coupling ζ25, it was necessary to include estimates of two further Coriolis terms to obtain a satisfactory interpretation of the data. Many vibration-rotation parameters and the dipole moments are determined. © 1983 Elsevier B.V. .
URIhttp://hdl.handle.net/10261/81827
DOI10.1016/0022-2852(83)90325-9
Identifiersdoi: 10.1016/0022-2852(83)90325-9
issn: 0022-2852
Appears in Collections:(CFMAC-IEM) Artículos
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