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Title

Experimental and theoretical study of line mixing in methane spectra. IV. Influence of the temperature and of the band

AuthorsPieroni, D.; Nguyen-Van-Thanh, C.; Brodbeck, C.; Hartmann, Jean-Michel; Gabard, T.; Champion, J.-P.; Bermejo, Dionisio ; Doménech, José Luis ; Claveau, C.; Valentin, A.
Issue Date2000
PublisherAmerican Institute of Physics
CitationJournal of Chemical Physics 113: 5776- 5783 (2000)
AbstractThe infrared bands line-mixing effects of methane perturbed by nitrogen were discussed at different pressures. The spectral shapes of the ν2, ν4 and ν3 bands were compared at room temperature while the ν3 region was employed for the investigation of thermal effects. The effects of collisions in the ν4 region's spectra were calculated at the room temperature. The Coriolis coupling between ν2 and ν4 vibrational states resulted in the failure of evolution modeling with increasing pressure of absorption.© 2000 American Institute of Physics
URIhttp://hdl.handle.net/10261/81347
DOI10.1063/1.1289243
Identifiersdoi: 10.1063/1.1289243
issn: 0021-9606
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