English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/80974
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:


Unveiling the reactivity of propargylic hydroperoxides under gold catalysis

AuthorsAlcaide, Benito ; Almendros, Pedro ; Quirós, M. Teresa; López, Ramón; Menéndez, María I.; Sochacka-Cwikla, Alesandra
Issue Date2013
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 135: 898- 905 (2013)
AbstractControlled gold-catalyzed reactions of primary and secondary propargylic hydroperoxides with a variety of nucleophiles including alcohols, phenols, 2-hydroxynaphthalene-1,4-dione, and indoles allow the direct and efficient synthesis of β-functionalized ketones. Moreover, the utility of some of the resulting products for the selective preparation of fused polycycles has been demonstrated. In addition, density functional theory (DFT) calculations and 18O-labeling experiments were performed to obtain an insight into various aspects of the controlled reactivity of propargylic hydroperoxides with external nucleophiles under gold catalysis. © 2012 American Chemical Society.
Identifiersdoi: 10.1021/ja3108966
issn: 0002-7863
e-issn: 1520-5126
Appears in Collections:(IQOG) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf15,38 kBAdobe PDFThumbnail
Show full item record
Review this work

Related articles:

WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.