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Stereoselective cyanation of 4-formyl and 4-imino-β-lactams: Application to the synthesis of polyfunctionalized γ-lactams

AuthorsAlcaide, Benito ; Almendros, Pedro ; Cabrero, Gema; Ruiz, M. Pilar
Issue Date2012
PublisherPergamon Press
CitationTetrahedron 68: 10761- 10768 (2012)
AbstractThe stereoselective reaction of 4-oxoazetidine-2-carbaldehydes and their corresponding imines with cyanide-based reagents give β-lactam α-aminonitriles, which are chameleonic building blocks for the controlled synthesis of a variety of new compounds including functionalized γ-lactams, succinimide derivatives, and diamino-lactams derivatives in optically pure form. © 2012 Elsevier Ltd. All rights reserved.
Identifiersdoi: 10.1016/j.tet.2012.02.062
issn: 0040-4020
Appears in Collections:(IQOG) Artículos
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