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Relaxation time distribution from time and frequency domain dielectric spectroscopy in poly(aryl ether ether ketone)

AuthorsBello, Antonio ; Laredo, Estrella; Grimau, Mario; Nogales, Aurora ; Ezquerra, Tiberio A.
Issue Date2000
PublisherAmerican Institute of Physics
CitationJournal of Chemical Physics 113: 863- 868 (2000)
AbstractA new application of the simulated annealing Monte Carlo procedure is presented and applied to the extraction of the relaxation time distribution from dielectric spectroscopy either in time or frequency domain. This decomposition method named simulated annealing direct signal analysis~SADSA!, is applied to computer generated curves, e(t), e8(v), and e9(v), by using the most widely accepted empirical distributions. The discretized distribution fits exactly the analytical expression which can be evaluated in these cases for the set of parameters used in the simulation. Also, both distribution functions are found to be identical which proves that the method is certainly converging to the right solution in both cases. Experimental results on amorphous poly~aryl ether ether ketone! for e(t), e8(v), and e9(v) are analyzed with SADSA and the obtained relaxation time distribution is used to go from time to frequency domain and reciprocally. The results are compared to those obtained by assuming a Havriliak–Negami profile for the distribution function. © 2000 American Institute of Physics
Identifiersdoi: 10.1063/1.481862
issn: 0021-9606
Appears in Collections:(CFMAC-IEM) Artículos
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