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Título: | Reactive fillers based on SWCNTs functionalized with matrix-based moieties for the production of epoxy composites with superior and tunable properties |
Autor: | González Domínguez, José Miguel CSIC ORCID ; Martínez Rubí, Yadienka; Díez-Pascual, Ana M. CSIC ORCID; Ansón Casaos, Alejandro CSIC ORCID ; Gómez-Fatou, Marián A. CSIC ORCID; Simard, Benoit; Martínez Fernández de Landa, María Teresa CSIC ORCID | Palabras clave: | Carbon nanotubes Epoxy Functionalisation Amines |
Fecha de publicación: | 21-jun-2012 | Editor: | Institute of Physics Publishing | Citación: | Nanotechnology 23(28): 285702 (2012) | Resumen: | Composite materials based on epoxy matrix and single-walled carbon nanotubes (SWCNTs) are able to exhibit outstanding physical properties improvements when using a tailored covalent functionalization with matrix-based moieties containing terminal amines or epoxide rings. The proper choice of grafted moiety 20 and integration protocol makes feasible to tune the composite physical properties. At 0.5 wt% SWCNT loading, these composites exhibit up to 65% improvement in storage modulus, 91% improvement in tensile strength, and 65% improvement in toughness. A 15ºC increase in the glass transition temperature regarding the parent matrix was also achieved. This suggests that a highly improved interfacial bonding between matrix and filler, coupled to improved dispersion are achieved. The degradation temperatures show an 25 upshift in the range of 40-60ºC, which indicates superior thermal performance. Electrical conductivity ranges from ~10-13 to ~10-3 S/cm, which also shows the possibility of tuning the insulating or conductive behaviour of the composites. The chemical affinity of the functionalization moieties with the matrix and the unchanged molecular structure at the SWCNT/matrix interface are responsible for such improvements. | Descripción: | 7 figures | Versión del editor: | http://dx.doi.org/10.1088/0957-4484/23/28/285702 | URI: | http://hdl.handle.net/10261/79227 | DOI: | 10.1088/0957-4484/23/28/285702 | Identificadores: | doi: 10.1088/0957-4484/23/28/285702 issn: 0957-4484 e-issn: 1361-6528 |
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Reactive fillers based....2012.pdf | 1,37 MB | Adobe PDF | Visualizar/Abrir |
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