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Título

High catalytic performance of palladium nanoparticles supported on multiwalled carbon nanotubes in alkene hydrogenation reactions

AutorCano, Manoli; Benito, Ana M. ; Maser, Wolfgang K. ; Urriolabeitia, Esteban P.
Palabras claveCarbon nanotubes
Palladium Nanoparticles
Hybrid materials
Catalysis
Hydrogenation reactions
Fecha de publicación2013
EditorRoyal Society of Chemistry (Great Britain)
CitaciónNew Journal of Chemistry 37(7): 1968-1972 (2013)
ResumenThe synthesis of Pd nanoparticles (Pd-NPs) supported on multiwalled carbon nanotubes (MWCNTs) and the catalytic performance of the resulting material (Pd-NPs/MWCNTs) on hydrogenation reactions are presented. Facile preparation approaches based on the decomposition of Pd precursors in the presence of MWCNTs lead to homogeneous dispersions of supported Pd-NPs with average size of 4 nm and Pd loads about 12%. The catalytic performance of this material was evaluated in hydrogenation reactions of α,β-unsaturated ketones, alkenes, cyclic di-, tri-and tetraenes, aromatic compounds, terpenes and terpenoids, resulting in very high activity offering short reaction times, high conversion rates, notable selectivity, and acceptable recyclabitiliy under mild conditions.
Descripción6 pages, 2 figures, 2 tables.- First published online 26 April, 2013
Versión del editorhttp://dx.doi.org/ 10.1039/C3NJ00183K
URIhttp://hdl.handle.net/10261/78954
DOI10.1039/C3NJ00183K
ISSN1144-0546
E-ISSN1369-9261
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