Please use this identifier to cite or link to this item:
http://hdl.handle.net/10261/7662
Share/Export:
![]() ![]() |
|
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Title: | Synthesis of p-cymene from limonene, a renewable feedstock |
Authors: | Martín-Luengo, María Ángeles CSIC ORCID ; Yates Buxcey, Malcolm CSIC ORCID; Martínez Domingo, M. J.; Casal, Blanca CSIC ; Iglesias, Marta CSIC ORCID ; Esteban, Miquel; Ruiz-Hitzky, Eduardo CSIC ORCID | Keywords: | Renewable feedstock Limonene p-Cymene Microwave irradiation Silica–aluminas Texture Acidity |
Issue Date: | 24-Jun-2008 | Publisher: | Elsevier | Citation: | Applied Catalysis B - Environmental 81(3-4): 218–224 (2008) | Abstract: | Highly selective limonene conversions to p-cymene in short reaction times were achieved under ‘‘solvent free’’ conditions over mesoporous silica–alumina supports heated by microwave irradiation. An increase in the silica content of these mixed oxides led to increases in the specific surface area, porosity (pore size and volume) and the surface acidity. The conversion and selectivity of limonene to p-cymene under microwave irradiation was also found to rise as the silica content in these mixed oxides was increased. By careful choice of the solid and reaction parameters the activities for the conversion of limonene and selectivity to p-cymene (used as an intermediate in fine chemical syntheses) could be fine tuned. Results are presented under both dry media and reflux conditions. | Publisher version (URL): | https://doi.org/10.1016/j.apcatb.2007.12.003 | URI: | http://hdl.handle.net/10261/7662 | DOI: | 10.1016/j.apcatb.2007.12.003 | ISSN: | 0926-3373 |
Appears in Collections: | (ICMM) Artículos |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
accesoRestringido.pdf | 15,38 kB | Adobe PDF | ![]() View/Open |
Review this work
SCOPUSTM
Citations
76
checked on May 8, 2022
WEB OF SCIENCETM
Citations
69
checked on May 15, 2022
Page view(s)
407
checked on May 16, 2022
Download(s)
75
checked on May 16, 2022
Google ScholarTM
Check
Altmetric
Dimensions
WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.