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Title

Enzyme catalysed tandem reactions

AuthorsOroz-Guinea, Isabel ; García-Junceda, Eduardo
KeywordsEnzyme catalysed
Multi-enzyme systems
Issue Date13-May-2013
PublisherElsevier
CitationCurrent Opinion in Chemical Biology 17(2) : 236-249 (2013)
AbstractTo transfer to the laboratory, the excellent efficiency shown by enzymes in Nature, biocatalysis, had to mimic several synthetic strategies used by the living organisms. Biosynthetic pathways are examples of tandem catalysis and may be assimilated in the biocatalysis field for the use of isolated multi-enzyme systems in the homogeneous phase. The concurrent action of several enzymes that work sequentially presents extraordinary advantages from the synthetic point of view, since it permits a reversible process to become irreversible, to shift the equilibrium reaction in such a way that enantiopure compounds can be obtained from prochiral or racemic substrates, reduce or eliminate problems due to product inhibition or prevent the shortage of substrates by dilution or degradation in the bulk media, etc. In this review we want to illustrate the developments of recent studies involving in vitro multi-enzyme reactions for the synthesis of different classes of organic compounds
Publisher version (URL)http://dx.doi.org/10.1016/j.cbpa.2013.02.015
URIhttp://hdl.handle.net/10261/76592
DOI10.1016/j.cbpa.2013.02.015
ISSN1367-5931
E-ISSN1879-0402
Appears in Collections:(IQOG) Artículos
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