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Title

Hydrogen peroxide decomposition in an environmentally friendly pickling solution for AISI 316L stainless steel

AuthorsNarváez, L.; Cano Díaz, Emilio ; Bastidas Rull, José María
Issue Date2005
PublisherNACE International
CitationCorrosion 61: 21-29 (2005)
AbstractThere is increasing interest in the utilization of ecological bath solutions for the pickling of stainless steel (SS), because conventional nitric (HNO3) and hydrofluoric (HF) acid mixtures generate high NOx emissions. A mixture of hydrogen peroxide (H 2O2), sulfuric acid (H2SO 4), and HF has been tested in this study as an environmentally friendly pickling solution for AISI 316L SS (UNS S31603 . The decomposition of H2O2 and the H 2SO4-HF-H2O2 mixture was assessed at different temperatures from 25°C to 60°C, with ferric ion contents from 0 to 40 g/L, with and without stirring of the aqueous acid mixture. Me p-Toluene sulfonic, 3-hydroxybenzoic, and 4-dodecylbenzene sulfonic acids were tested as stabilizers for H 2O2. The AISI 316L SS pickling rate found at 50°C was 2.35 × 103 mg/dm2-day (mdd) and 0.12 × 103 mdd, respectively, in the absence and presence of 40 g/L ferric ion. © 2005, NACE International.
URIhttp://hdl.handle.net/10261/76582
DOIhttp://dx.doi.org/10.5006/1.3278156
Identifiersdoi: 10.5006/1.3278156
issn: 0010-9312
Appears in Collections:(CENIM) Artículos
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