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Title

Control of nitrogen insertion during the growth of nitrogen-containing carbon nanofibers on cordierite monolith walls

AuthorsRoldán, Laura; Armenise, Sabino; Marco, Yanila; García-Bordejé, José Enrique
KeywordsNitrogen-doping
Carbon nanofibers
Monolith
Issue Date2012
PublisherRoyal Society of Chemistry
CitationPhysical Chemistry Chemical Physics 14: 3568- 3575 (2012)
AbstractA well attached coating of nitrogen-functionalised carbon nanofibers (N-CNFs) has been prepared on the walls of cordierite monolith channels. It is formed via concurrent decomposition of ethane and ammonia catalysed by nickel nanoparticles dispersed on alumina coated cordierite monolith. N-CNF/monoliths synthesis employing several growth temperatures and NH 3 compositions was exhaustively characterised by Raman, XPS, elemental analysis and TEM. Synthesis conditions affected profoundly content and type of nitrogen functionality, enabling its fine tuning. N-CNFs surface chemistry and microstructure differed remarkably from its N-free counterparts.
DescriptionFirst published online Jan. 16, 2012
Publisher version (URL)http://dx.doi.org/10.1039/c2cp23609e
URIhttp://hdl.handle.net/10261/76278
DOI10.1039/c2cp23609e
Identifiersdoi: 10.1039/c2cp23609e
issn: 1463-9076
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