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Título: | Dynamics of NeI2 system in the infinite order sudden approximation (IOSA): a quantum mechanical close coupling treatment |
Autor: | Cortina, A.M. CSIC; Miret-Artés, Salvador CSIC ORCID; Villarreal, Pablo CSIC ORCID; Delgado Barrio, Gerardo CSIC ORCID | Fecha de publicación: | 1986 | Editor: | Elsevier | Citación: | Journal of Molecular Structure 142: 513- 516 (1986) | Resumen: | We study in this work the vibrational predissociation (VP) of the van der Waals (vdW) molecule NeI2(B). We take advantage of the large difference existing between fast vibrational and slow rotational motions within the complex. Hence, energy levels and rates for VP are obtained as functions of γ, the angle describing the relative atom-diatom orientation, through the formalism of coupled equations. Afterthat, three-dimensional values are reached by average on the orientations. This approach, close to the >infinite order sudden> approximation, leads to results in agreement with so-called >energy gap law> when compared with the corresponding ones for HeI2(B). © 1986. | URI: | http://hdl.handle.net/10261/75364 | DOI: | 10.1016/0022-2860(86)85169-9 | Identificadores: | doi: 10.1016/0022-2860(86)85169-9 issn: 0022-2860 |
Aparece en las colecciones: | (CFMAC-IEM) Artículos |
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