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Ruthenium Nanoparticles Stabilized by N-Heterocyclic Carbenes: Ligand Location and Influence on Reactivity

AuthorsLara, Patricia ; Rivada-Wheelaghan, Orestes ; Conejero, Salvador ; Poteau, Romuald; Philippot, Karine; Chaudret, Bruno
Issue Date2011
PublisherJohn Wiley & Sons
CitationAngewandte Chemie - International Edition 50: 12080- 12084 (2011)
AbstractNHCs go nano: Ruthenium nanoparticles were formed from (cyclooctadiene)(cyclooctatriene)ruthenium(0) and stabilized by N-heterocyclic carbenes (NHCs). Solid-state NMR spectroscopy revealed both the coordination of the NHC ligands on the surface of the particles and their surface reactivity.
Identifiersdoi: 10.1002/anie.201106348
issn: 1433-7851
Appears in Collections:(IIQ) Artículos
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