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Title

Gas phase molecular relaxation at very low temperatures. A comparative study of N2 and its mixtures with He and Ne

AuthorsAoiz, F. Javier ; Bañares, Luis; Herrero, Víctor J. ; Martínez-Haya, Bruno; Menéndez, M.; Quintana, P.; Tanarro, Isabel ; Verdasco, E.
Issue Date2002
PublisherElsevier
CitationVacuum 64: 417- 423 (2002)
AbstractThe low temperature ( < 100K) relaxation of N2 in self-collisions and in collisions with He and Ne has been experimentally studied with resonance-enhanced-multiphoton-ionization and time-of-flight techniques. The following average values of the rotational relaxation cross sections, σr, have been derived from the measurements: σr N2-N2 (T = 5-60 K) ≈ 35 Å2; σr N2-He (T = 5-80 K) ≈ 15 Å2 and σr N2-Ne (T = 5-60 K) ≈ 40 Å2. The cross section trend σr N2-N2 ≈ σr N2-Ne > σr N2-He reported in the literature for T = 300K is confirmed below 100K, but the absolute values are larger in the low temperature range. © 2002 Elsevier Science Ltd. All rights reserved.
Description13 pags. 3 figs.
Publisher version (URL)http://dx.doi.org/10.1016/S0042-207X(01)00298-6
URIhttp://hdl.handle.net/10261/74870
DOI10.1016/S0042-207X(01)00298-6
Identifiersdoi: 10.1016/S0042-207X(01)00298-6
issn: 0042-207X
Appears in Collections:(CFMAC-IEM) Artículos
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