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http://hdl.handle.net/10261/74168
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dc.contributor.author | Vries, Richard F. de | - |
dc.contributor.author | Iglesias, Marta | - |
dc.contributor.author | Snejko, Natalia | - |
dc.contributor.author | Álvarez-García, Susana | - |
dc.contributor.author | Gutiérrez-Puebla, Enrique | - |
dc.contributor.author | Monge, M. Ángeles | - |
dc.date.accessioned | 2013-04-11T11:49:02Z | - |
dc.date.available | 2013-04-11T11:49:02Z | - |
dc.date.issued | 2012 | - |
dc.identifier | doi: 10.1039/c1jm14677g | - |
dc.identifier | issn: 0959-9428 | - |
dc.identifier.citation | Journal of Materials Chemistry 22: 1191-1198 (2012) | - |
dc.identifier.uri | http://hdl.handle.net/10261/74168 | - |
dc.description.abstract | The first series of mixed succinate/sulfate/Ln MOFs, [Ln2(C 2H4C2O4)2(SO 4)(H2O)2] (RPF-16), where Ln = La, Pr, Nd, and Sm, were hydrothermally obtained and their structures determined by X-ray single crystal diffraction. The crystalline products are a series of isostructural 3D polymeric compounds that crystallise in the monoclinic space group P2(1)/n. Their framework comprises infinite crossing chains of LnO9 sharing edges polyhedra, kept together by succinate and sulfate anions. Topological simplification gives rise to a 3D uninodal six connected net of type pcu alpha-Po primitive cubic. These well-defined compounds show high chemoselectivity towards reduction of the nitro group and present bifunctional activity for the one-pot reductive amination of heptanal at near-complete conversion of the substrates. A general overview of the room-temperature luminescence behavior in the new RPF-16 Ln materials is also reported. © The Royal Society of Chemistry 2011. | - |
dc.description.sponsorship | The authors thank A. E. Platero-Prats for her comments on the topological studies. R.D. acknowledges a FPI scholarship from Spanish Ministry of Science and Innovation (MICIN), and Fondo Social Europeo from the EU. This work has been supported by the Spanish MCYT Project Mat 2007-60822 FAMA and Consolider-Ingenio CSD2006-2001. S.A.G. thanks the CSIC for a postdoctoral contract (Program JAE-DOC). | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry (UK) | - |
dc.relation | S2009/MAT-1756 PHAMA | - |
dc.rights | closedAccess | - |
dc.title | Mixed lanthanide succinate-sulfate 3D MOFs: Catalysts in nitroaromatic reduction reactions and emitting materials | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1039/c1jm14677g | - |
dc.date.updated | 2013-04-11T11:49:03Z | - |
dc.description.version | Peer Reviewed | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.fulltext | No Fulltext | - |
item.languageiso639-1 | en | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.openairetype | artículo | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | none | - |
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