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A close-coupling infinite order sudden approximation (IOSA) to study vibrational predissociation of the HeI2 van der Waals molecule

AuthorsDelgado Barrio, Gerardo ; Mareca, P.; Villarreal, Pablo ; Cortina, A. M.; Miret-Artés, Salvador
Issue Date1986
PublisherAmerican Institute of Physics
CitationJournal of Chemical Physics 84: 4268- 4271 (1986)
AbstractWe apply in this paper a model related to the >infinite order sudden approximation> to treat the vibrational predissociation of the HeI 2 van der Waals molecule. For each configuration, the stretching motions within the complex are exactly solved in the close-coupling formalism. The bending motion is then considered in an approximate way and averaged predissociation rates are obtained. Our results are compared with the experiment and also with previous models. © 1986 American Institute of Physics.
Identifiersdoi: 10.1063/1.450048
issn: 0021-9606
Appears in Collections:(CFMAC-IEM) Artículos
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