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Lanthanoid single-ion magnets based on polyoxometalates with a 5-fold symmetry: The series [LnP5W30O110]12– (Ln3+ = Tb, Dy, Ho, Er, Tm, and Yb)

AuthorsCamón, Agustín; Evangelisti, Marco; Luis, Fernando; Martínez Pérez, M. J.; Sesé Monclús, Javier
Issue Date2012
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 134(36): 14982-14990 (2012)
AbstractA robust, stable and processable family of mononuclear lanthanoid complexes based on polyoxometalates (POMs) that exhibit single-molecule magnetic behavior is described here. Preyssler polyanions of general formula [LnP 5W 30O 110] 12- (Ln 3+ = Tb, Dy, Ho, Er, Tm, and Yb) have been characterized with static and dynamic magnetic measurements and heat capacity experiments. For the Dy and Ho derivatives, slow relaxation of the magnetization has been found. A simple interpretation of these properties is achieved by using crystal field theory. © 2012 American Chemical Society.
Identifiersdoi: 10.1021/ja305163t
issn: 0002-7863
e-issn: 1520-5126
Appears in Collections:(ICMA) Artículos
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