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dc.contributor.authorMárquez, José M.-
dc.contributor.authorMartínez-Castro, Elisa-
dc.contributor.authorGabrielli, Serena-
dc.contributor.authorLópez, Óscar-
dc.contributor.authorMaya, Inés-
dc.contributor.authorAngulo-Álvarez, Manuel-
dc.contributor.authorÁlvarez, Eleuterio-
dc.contributor.authorFernández-Bolaños, José G.-
dc.identifierdoi: 10.1039/c1cc11345c-
dc.identifierissn: 1359-7345-
dc.identifier.citationChemical Communications 47: 5617- 5619 (2011)-
dc.description.abstractWe report the synthesis of the hitherto unknown zwitterionic alkoxyamino cyanoboranes by reduction of O-alkyloximes with sodium cyanoborohydride; unprecedented cyanoboronated N-alkoxyformamidines were also isolated as by-products. Boronated alkoxyamines were found to be efficient cyanoborane transfer agents towards more basic amines, including aminosugars; they were also successfully transformed into neoglycoconjugates by the neoglycorandomization reaction with reducing sugars. © 2011 The Royal Society of Chemistry.-
dc.description.sponsorshipWe thank the Dirección General de Investigación of Spain (CTQ2008 02813 and Integrated Action HI-2006-0131) and Junta de Andalucía (FQM 134) for financial support. J.M.M. and E.M.-C. thank MICINN for grants.-
dc.publisherRoyal Society of Chemistry-
dc.titleAlkoxyamine-cyanoborane adducts: Efficient cyanoborane transfer agents-
dc.description.versionPeer Reviewed-
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