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Alkoxyamine-cyanoborane adducts: Efficient cyanoborane transfer agents

AuthorsMárquez, José M.; Martínez-Castro, Elisa; Gabrielli, Serena; López, Óscar; Maya, Inés; Angulo-Álvarez, Manuel; Álvarez, Eleuterio ; Fernández-Bolaños, José G.
Issue Date2011
PublisherRoyal Society of Chemistry
CitationChemical Communications 47: 5617- 5619 (2011)
AbstractWe report the synthesis of the hitherto unknown zwitterionic alkoxyamino cyanoboranes by reduction of O-alkyloximes with sodium cyanoborohydride; unprecedented cyanoboronated N-alkoxyformamidines were also isolated as by-products. Boronated alkoxyamines were found to be efficient cyanoborane transfer agents towards more basic amines, including aminosugars; they were also successfully transformed into neoglycoconjugates by the neoglycorandomization reaction with reducing sugars. © 2011 The Royal Society of Chemistry.
Identifiersdoi: 10.1039/c1cc11345c
issn: 1359-7345
Appears in Collections:(IIQ) Artículos
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