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A spin crossover ferrous complex with ordered magnetic ferric anions

AuthorsRoubeau, Olivier; Evangelisti, Marco; Natividad, Eva
Issue Date2012
PublisherRoyal Society of Chemistry (Great Britain)
CitationChemical Communications 48(61): 7604-7606 (2012)
AbstractThe first tetrahaloferrate spin crossover compound, [Fe(Metz) 6](FeBr 4) 2 (Metz = 1-methyltetrazole), is reported. The FeBr 4 - ions form ferromagnetically coupled 1D stacks and exhibit an antiferromagnetic order at 2.2 K, which coexists with the gradual spin crossover centred at 165 K. © 2012 The Royal Society of Chemistry.
DescriptionEl pdf del artículo es la versión post-print.
Publisher version (URL)http://dx.doi.org/10.1039/C2CC33709F
Identifiersdoi: 10.1039/C2CC33709F
issn: 1359-7345
e-issn: 1364-548X
Appears in Collections:(ICMA) Artículos
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